An example of silicate material is glass. Remember that silica is represented as SiO2.So compounds containing silica & silicates are attacked by hydrogen fluoride gas or its aqueous solution. When reacted with HF gas, SiF4 gas is evolved. This is represented as
SiO2 + 4HF--->2H2O + SiF4.
But in solutions H2SiF6 is formed. This is given as
SiO2 + 6HF----> H2SiF6 + 2H2O.
Etching means the attack of HF on glass.
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